MATERIAL SAFETY DATA SHEET
IMR POWDER COMPANY
(Click HERE for Printable Version)
Trail Boss smokeless powder is manufactured
for Hodgdon Powder Company by ADI, Ltd.:
Revised: 31 March 2004
MULWALA PROPELLANT AS-25 BP
Issue Date: 31 March 2004
Statement of Hazardous Nature
IDENTIFICATION
Not Hazardous According to Worksafe Australia
Criteria.
Supplier
Company: ADI Limited
Address: Bayly Street
Mulwala NSW 2647 AUS
Telephone: (+61 3) 5742 2200
Emergency Tel: (+61 3) 5742 2200
Fax: 03 5744 1873
SYNONYMS
Smokeless powder, Pistol propellant, Pistol powder
SHIPPING NAME
POWDER, SMOKELESS (SMOKELESS POWDER)
Product Name: Mulwala Propellant AS25 BP
Other Names: Pistol Propellant AS 25 BP
CAS RN No (s): None
UN Number: 0161
Packing Group None
Dangerous Goods Class: 1.3C
Subsidiary Risk: None
Hazchem Code: E
Poisons Schedule Number: None
USE
Porous single base smokeless powder or propellant for pistol ammunition.
Used according to
manufacturers directions.
PHYSICAL DESCRIPTION/PROPERTIES
APPEARANCE
Small gray, gray green disk shaped granules. Insoluble in water.
WARNING: SEVERE EXPLOSION HAZARD. Detonation may occur from heavy impact
or excessive heating. Avoid all contact with other chemicals.
Boiling Point (0C): Not available.
Melting Point (0C): >170 decomposes
Vapor Pressure: (kPa): Negligible
Specific Gravity: Approx. 0.6
Flash Point (0C): Not applicable
Lower Explosive Limit (%): Not applicable
Upper Explosive Limit (%): Not applicable
Page 1MATERIAL SAFETY DATA SHEET
MULWALA PROPELLANT AS-25 BP
Issue Date: 31 March 2004
Solubility in Water (g/L): Immiscible
INGREDIENTS
Name
Nitrocellulose
Dibutyl Phthalate
Diphenylamine
Potassium Nitrate
Graphite
HEALTH HAZARD
ACUTE HEALTH EFFECTS
SWALLOWED
The material is harmful if swallowed
Considered an unlikely route of entry in commercial/industrial environments.
EYE
The material may be discomforting to the eyes
The material may produce moderate eye irritation leading to inflammation.
Repeated or prolonged exposure to irritants may produce conjunctivitis.
SKIN
The material may be discomforting to the skin if contact is prolonged and is capable of
causing skin reactions which may lead to dermatitis and the material contains a component
that may be absorbed through the skin and may cause headache, nausea if exposure is
prolonged and may rarely cause allergic skin reactions.
Bare unprotected skin should not be exposed to this material. The material may accentuate
any preexisting dermatitis condition.
INHALED
Particulate/dust is slightly discomforting to the upper respiratory tract if inhaled.
The detonation/decomposition vapors are toxic and harmful if inhaled.
CHRONIC HEALTH EFFECTS
Principal routes of exposure are usually by skin contact with the material and inhalation of
generated dust.
As with any chemical product, contact with unprotected bare skin; inhalation of vapor, mist
or dust in work place atmosphere; or ingestion in any form, should be avoided by observing
good occupational work practice.
The principal hazard is related to the potential of fire/explosion hazard with associated
physical injury and toxic fume inhalation.
FIRST AID
SWALLOWED
• For advice, contact a Poisons Information Canter or a doctor at once.
• Urgent hospital treatment is likely to be needed.
• If swallowed do NOT induce vomiting.]
• If vomiting occurs, lean patient forward or place on left side (head-down
position, if possible) to maintain open airway and prevent aspiration.
• Observe the patient carefully.
• Never give liquid to a person showing signs of being sleepy or with reduced
• awareness; i.e. becoming unconscious.
• Give water to rinse out mouth, then provide liquid slowly and as much as
• casualty can comfortably drink.
• Transport to hospital or doctor without delay.EYE
If this product come in contact with eyes:
• Immediately hold eyelids apart and flush the eye continuously with running water.
• Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and
• continue flushing until advised to stop by the Poisons Information Center or a doctor,
• or for at least 15 minutes.
• Transport to hospital or doctor without delay.
• Removal of contact lenses after an eye injury should only be undertaken by skilled
• personnel.SKIN
• Immediately remove all contaminated clothing, including footwear.
• Flush skin and hair with running water (and soap if available).
• Seek medical attention in event of irritation.INHALED
• If fumes or combustion products are inhaled remove from contaminated area.
• Lay patient down. Keep warm and rested.
• Prostheses such as false teeth, which may block airway, should be removed, where
• possible, prior to initiating first aid procedures.
• Apply artificial respiration if not breathing, preferably with a demand vale
• resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if
• necessary.
• Transport to hospital, or doctor.
PRECAUTIONS FOR USE
EXPOSURE STANDARDS
None assigned. Refer to individual constituents.
INGREDIENT DATA
NITROCELLULOSE:
TLVTWA: 10 mg/m 3 (Value for particulate matter containing no asbestos and ,1% crystalline
silica, Inhalable fraction) [ACGIH]
TLVWA: 3mg/m3 (Value for particulate matter containing no asbestos and <1% crystalline
silica, Respirable fraction) [ACGIH]
No exposure limits set by NIOSH or ACGIH as dust not otherwise classified
dusts not otherwise classified, as inspirable dust;
ES TWA: 10 mg/m3
GRAPHITE:
TLV TWA: 2 mg/rn3 (Respirable fraction) [ACGIH]
PEL Total dust: 15mg/rn3 {OSHA Zi]
PEL Respirable fraction: 5mg/rn3 [OSHA Zi] graphite, all forms except graphite fibers
TLV TWA 2 mg/rn3 (respirable dust)
ES TWA: 3 mg/in3 (respirable dust) OES TWA: 10 mg/in3 total inhalable dust
OES TWA: 4 mg/rn3 respirable dust
MAK value: 1.5 mg/rn3 measured as the respirable fraction of the aerosol and BAT values are observed.
MAK values, and categories and groups are those recommended within the Federal Republic of Germany
Graphite pneumoconiosis resembles coal workers' pneumoconiosis. Data indicate that the higher the crystalline silica content of graphite the more likely the disease will increase in severity. The presence of anthracite coal in the production of synthetic graphite appears to make arbitrary the use of the term, "synthetic", "artificial" or "natural".
POTASSIUM NITRATE:
No exposure limits set by NOHSC or ACGIH
Dusts not otherwise classified, as inspirable dust:
ES TWA: 10 mg/rn3
DIBUTYL PHTHALATE:
TLV TWA: 5 mg/in3 [ACGIH]
PEL TWA: 5 mg/in3 [OSHA ZI]
ES TWA: 5 mg/rn3
TLV TWA: 5 mg/in3
CES TWA: 5 mg/rn3 STEL: 10 mg/rn3
IDLH Level: 4000 mg/in3
In animal testing the reproductive system has been the prime target.Exposure at or below the TLV has not caused either systemic effects or irritation in man.
ENGINEERING CONTROLS
Use in a well-ventilated area General exhaust is adequate under normal operating conditions. Local exhaust ventilation mat be required in specific circumstances. If risk of overexposure exists, wear approved respirator. Correct fit is essential to obtain adequate protection. Provide adequate ventilation in warehouse or closed storage areas. Air contaminants generated in the workplace possess varying "escape" velocities which, in turn, determine the "capture velocities" of fresh circulating air required to effectively remove the contaminant.
PERSONAL PROTECTION
EYE
Wear glasses with side shields.
Chemical goggles.
Contact lenses pose a special hazard; soft lenses may absorb irritants and all
lenses concentrate them. DO NOT wear contact lenses.HANDS/FEET
Wear protective gloves, e.g.. PVC.
Manufacture may require:
Protective footwearOTHER
Overalls
Eyewash unit
Manufacture may require:
Non-static clean room clothing
Impervious apron
Ensure there is ready access to a safety shower
Barrier cream
SAFE HANDLING
STORAGE AND TRANSPORT
SUITABLE CONTAINER
Australian Explosives Code Method E22
Inner: Bags, paper/plastic/textile
Receptacles, fiberboard/plastics
Outer: Boxes, fiberboard/wood. Drums, steel/fiberboard/plywood.
Check containers are clearly labeled.
Packaging as recommended by manufacturer.STORAGE INCOMPATIBILITY
Segregate from strong acids strong alkalis and strong oxidizers. Avoid contact with other explosives, pyrotechnics, solvents, adhesives, paints, cleaners and unauthorized metals, plastics, packing equipment and materials. Avoid contamination with a acids, alkalis, reducing agents, amines and phosphorus.
STORAGE REQUIREMENTS
Observe manufacturer's storing and handling recommendations. Store in original containers. Keep dry No smoking, naked lights, heat or ignition sources. Store cases in a well ventilated magazine license for IMCO Class 1.30 Explosives Keep storage area free of debris, waste and combustibles. Protect containers against physical damage. Check regularly for spills and leaks NOTE: If deterioration of the explosive occurs or large quantities of explosive need to be destroyed notify the Manager, AOL Mulwala Facility or
TRANSPORTATION
Class 1 - Explosives shall not normally be carried on the same vehicle with dangerous goods of other classes. Segregation shall in any case be in accordance with the applicable Commonwealth, State or Territory explosives legislation. A Class 1 (Explosives) listing in ACTOG does not authorize transport in Australia and no entry may be interpreted to this effect unless specified by Commonwealth, State or Territory legislation. The requirements of Section 10 of the ACTDG have no force in respect to Commonwealth (Armed Services) explosives. In transporting mixed loads of Class 1 explosive substances and/or articles the extent of mixing is determined by the Compatibility Grouping Letter. Dangerous Goods of the same Compatibility A->K may only be transported together provided that the whole load is treated as belonging to the Division having the smaller number. Compatibility Group Letters C, O and E may be carried in the same unit load with an assigned Compatibility Group Letter of E.
SPILLS AND DISPOSAL
MINOR SPILLS
Clean up all spills immediately. Remove all ignition sources. Avoid contact with skin and eyes. Wear impervious gloves and safety glasses.
Use spark-free tools when handling
Place spilled material in clean, dry, sealable, labeled container.
Flush spill area with water.MAJOR SPILLS
Clear area of personnel. Restrict access to area. Alert Fire Brigade and tell them location and nature of hazard. May be violently or explosively reactive. Wear full body protective clothing with breathing apparatus. Prevent, by any means available, spillage from entering drains and water course.
SAFE HANDLING
Consider evacuation (or protect in place).In the case of transport accident notify the State Police, State Explosives Inspector and the Manufacturer, AOI Mulwala Facility No smoking or naked lights within area. Shut off all possible sources of ignition and increase ventilation. Stop leak if safe to do so.
Collect recoverable packages and segregate from loose, spilled material contamination of drains or waterways occurs, advise emergency services. Collect, using a spark-free shovel,, and seal in labeled drums for disposal Wash spill area with large quantities of water. Protective clothing and equipment should be washed down after use and laundered separately from non-contaminated materials.
DISPOSAL
Do not burn. Consult an explosives manufacturer for recommended methods of destroying explosives materials so as to minimize effects on the environment. Comply with applicable national and local laws. In the United States, comply with applicable Federal Regulations under the authority of the Resource Conservation and Recover Act (40 CFR, parts 260-271).
FIRE FIGHTERS-REPORT
EXTINGUISHING MEDIA
DANGER: Deliver media remotely For minor fires: Flooding quantities only. For large fires: Do not attempt to extinguish
FIRE FIGHTING
WARNING: EXPLOSIVE MATERIAL/ARTICLES PRESENT!
Evacuate all personnel and move upwind.
Prevent re-entry
Alert Fire Brigade and tell them location and nature of hazard.
May be explosively reactive, detonate and release much heat.
Wear full-body protective clothing with breathing apparatus.
Prevent, by any means available, spillage and fire effluent from entering drains or watercourses.
Fight from safe distances and protected locations.
Use flooding quantities of water.
DO NOT approach containers suspected to be hot.
Cool any exposed containers not involved in fire from protected locations. Equipment should be thoroughly decontaminated after use.FIRE EXPLOSION HAZARD
WARNING: HIGH EXPLOSION HAZARD!
• Combustible
• Dry material is extremely sensitive to shock, friction, heat and sparks.
• Avoid metal to metal contact
• Heat may cause expansion and decomposition leading to violent rupture of containers
• Heat affected containers remain hazardous
• May detonate in a mass explosion particularly if confined or mixed with incompatible materials.
• Explosives can supply own oxygen for combustion and smothering action of foam or dry chemical maybe in ineffective.
• May emit irritating, poisonous or corrosive fumes
• Combustion or decomposition produces oxides of nitrogen (Nox), carbon monoxide (CO) and carbon dioxide (CO2).FIRE INCOMPATIBILITY
Avoid contact with other explosives, pyrotechnics, solvents, adhesives, paints,
cleaners and unauthorized metals, plastics, packing equipment and materials. Avoid
contamination with acids, alkalis, reducing agents, amines and phosphorus.HAZCHEM E
CONTACT POINT
COMPANY CONTACT
(+61 3) 5742 2200
AUSTRALIAN POISONS INFORMATION CENTER
24 HOUR SERVICE:
POLICE, FIRE BRIGADE OR AMBULANCE: 000
NEW ZEALAND POISONS INFORMATION CENTER
24 HOUR SERVICE:
NZ EMERGENCY SERVICES: 11