MATERIAL SAFETY DATA SHEET
IMR POWDER COMPANY
IDENTIFICATION
NAME: DOUBLE BASE SMOKELESS POWDER
Trade Names and Synonyms:
SS ####, RF ####, HI-SKOR
####= Number Designation for Products
MANUFACTURER
Product Information Phone: (913) 362-9455
HAZARDOUS COMPONENTS
CHEMICAL
CAS NUMBER
Nitrocellulose
94004-70-0
Nitroglycerine
55-63-0
PHYSICAL DATA
Specific Gravity:
1.65
Solubility in H20: Negligible
Color:
Gray.
Form:
Perforated or non perforated small discs.
HAZARDOUS REACTIVITY
INSTABILITY:
Unstable with heat, Unstable with static charges. Unstable with
impact. Not hazardous if product used properly.
INCOMPATIBILITY:
Incompatible with acids, alkalis, oxidants.
DECOMPOSITION:
Decomposes with heat. Hazardous gases produce are carbon monoxide.
Decomposes with impact, static charges.
POLYMERIZATION:
Polymerization will not occur.
FIRE AND EXPLOSION DATA
Ignition temperature: 160-170 degC
FIRE AND EXPLOSION HAZARDS
Hazardous gases produced in fire are carbon monoxide 1.3C (DOT),
>100 lbs
Flammable Solid, 100 lbs. or less. Burns uncontrollably. Produces
shrapnel if confined.
EXTINGUISHING MEDIA
None
SPECIAL FIRE FIGHTING INSTRUCTIONS
Do not fight fire. Isolate area. Evacuate personnel to a safe
area.
Guard against intruders.
HEALTH HAZARD INFORMATION
PRINCIPAL HEALTH HAZARDS
These products have not been tested for toxicity. They are 1.3C
Explosives and burning, confined or unconfined, can cause physical injury,
including death. The toxicity effects given below for the hazardous components
may result from gross chronic or acute overexposure to the products by
inhalation, eye or skin contact or ingestion.
NITROGLYCERINE
Oral LD50: 525 mg/kg in rats
Human health effects from overexposure by inhalation, skin or eye contact, or ingestion may initially include headaches and temporary lowering of blood pressure. High exposures may lead to temporary nervous system depression, with anesthetic effects such as dizziness, confusion, or in coordination; reduction of the blood's oxygen carrying capacity with cyanosis, weakness, or shortness of breath; and death from gross overexposure. Evidence suggests that skin permeation can occur in amounts capable of producing the effects of systemic toxicity. Epidemiological studies suggest that this compound may pose a risk of some diseases of the circulatory system to humans. Individuals with pre-existing diseases of the central nervous system or cardiovascular system may have increased susceptibility to the toxicity of excessive exposures.
NITROCELLULOSE
Oral LD50: >5,000 mg/kg in rats
The compound is not a skin or eye irritant.
CARCINOGENICITY
None of the component(s) of this material is listed as a carcinogen
by HTP, IARC, or OSHA
EXPOSURE LIMITED
TLV* (ACGIH) : None established.
PEL (OSHA) : None established.
*TLV is a registered trademark.
Nitroglycerine: TLV (ACGIH) 0.05ppm, Skin
PEL
(OSHA) 0.2ppm, Skin, C
SAFETY INFORMATION
SAFETY PRECAUTIONS
Avoid contact with eyes. Avoid contact with
skin. Avoid contact with clothing. Avoid breathing dust. Wash thoroughly
after handling. Wash clothing after use. Avoid breathing powder fumes.
Keep out of reach of children.
FIRST AID
INHALATION:
If inhaled, remove to fresh air. If not breathing, give artificial
respiration, preferably mouth-to-mouth. If breathing is difficult, give
oxygen. Call a physician.
SKIN CONTACT:
In case of contact, wash with soap and plenty of water.
EYE CONTACT
In case of contact, immediately flush eyes with plenty of water
for at least 15 minutes. Call a physician.
INGESTION
If swallowed, induce vomiting immediately by giving two glasses
of water and sticking finger down throat. Never give anything by mouth
to an unconscious person. Call a physician.
NOTE: Burning smokeless powder may cause extensive and deep burns. Get medical attention immediately. Immerse burned area in cold water.
PROTECTION INFORMATION
GENERALLY APPLICABLE CONTROL MEASURES AND PRECAUTIONS
Use only with adequate ventilation. Keep away from heat, sparks and flames.
Keep container in a cool place. Keep container tightly closed. Avoid dust
generation. Do not mix with acids, alkalis. Do not consume food, drink
or tobacco in areas where they may become contaminated with this material.
Use spark proof tools and equipment. Do not allow powder to accumulate
in exhaust system.
PERSONAL PROTECTIVE EQUIPMENT
Safety glasses. Protective cotton gloves.
SPILL, LEAK, OR RELEASE
Review FIRE AND EXPLOSION HAZARDS AND SAFETY PRECAUTIONS before proceeding with clean up. Use appropriate PERSONAL PROTECTIVE EQUIPMENT during clean up.
Control access to area. Remove source of heat, sparks, flames, impact, friction or electricity. Pick up by hand for disposal. Do not use power equipment. Do not use damaged or wet material. Never return to container for reuse. Use nonsparking tools for clean up.
WASTE DISPOSALSHIPPING INFORMATION
Check manufacturer or shipper for specific information.
STORAGE CONDITIONS
Store in well ventilated area. Store in cool place. Keep container tightly closed. Do not store with other explosives. Store in accordance with National Fire Protection Assoc. regulations. Store in accordance with Federal Regulations. Do not store or consume food, drink, or tobacco in areas where they may become contaminated with this material. Store in approved type magazine.
ADDITIONAL INFORMATION AND REFERENCES
PERSONS HANDLING EXPLOSIVES MUST BE TRAINED IN THE CORRECT PROCEDURES
FOR THEIR USE.
General exhaust is adequate under normal operating conditions.
Local exhaust ventilation may be required in specific circumstances.
If risk of overexposure exists, wear approved respirator.
Correct fit is essential to obtain adequate protection.
Provide adequate ventilation in warehouse or closed storage areas.
Date of latest Revision: May, 1, 2001
Person Responsible for MSDS: Product Manager
Address: P.O. Box 2932
Shawnee Mission, KS 66201
Telephone: (913) 362-9455